Angew. Chem.誌の巻頭論文として掲載

デンドリマーで精密合成したロジウム-鉄合金ナノ粒子の触媒活性に関する論文がAngew. Chem.誌に掲載され、巻頭論文(Frontispiese)に採用されました。

A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes

I. Nakamula, Y. Yamanoi, T. Imaoka, K. Yamamoto, H. Nishihara
Angew. Chem. Int. Ed. 2011, 50, 5830-5833.

A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes

Mix and more than match: Relative to the catalytic activity of pure Rh nanoparticles in a dendrimer cage, Rh/Fe bimetallic nanoparticles in dendrimers have improved catalytic activity towards the hydrogenation of olefins, and unlike Wilkinson catalyst could catalyze nitroarene hydrogenation (see scheme, G4=4th generation dendrimer).